Product ID:40727-5 N,N-DIMETHYLANILINE
MSDS Date:09/13/1995
FSC:6810
NIIN:00D003999
MSDS Number: BXVGH

ALDRICH CHEMICAL CO INC

1001 WEST SAINT PAUL AVENUE
MILWAUKEE, WI 53201
US

Emergency Phone: 414-273-3850

Info Phone: 414-273-4979

Cage: 60928

ALDRICH CHEMICAL CO INC

355 MILWAUKEE, WI 53233 US

Telephone: 414-273-3850

Cage: 60928

DIMETHYLANILINE (N,N-DIMETHYL-ANILINE) (SARA 313) (CERCLA)

CAS: 121-69-7

RTECS: BX4725000

Fraction By Weight: 99.5%

OSHA PEL S, 5 PPM

ACGIH TLV: S,5 PPM/10 STEL;9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1410 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF INHALED,
SWALLOWED, OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO
EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN
IRRITATION AND EYE DAMAGE. SKIN ABSO RTION FORMS
METHEMGLOBIN/CYANOSIS. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY
CAUSE CANCER.
Explanation of Carcinogenicity:IARC LISTS N,N-DIMETHYLANILINE AS A
GROUP 3 SUSPECT CARCINOGEN-LIMITED LAB ANIMAL EVIDENCE; INADEQUATE
HUMAN EVIDENCE.
Effects of Overexposure:INHALED-CYANOSIS, COUGHING, SNEEZING, SHORTNESS
OF BREATH, UNCONSCIOUSNESS. EYES-TEARING, REDNESS OF EYES, BURNING
SENSATION, BLURRED VISION. SKIN-CYANOSIS, BURNING/ITCHING.
INGESTED-NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES-FLUSH WITH LOTS OF WATER FOR 15 MINUTES, HOLD LIDS OPEN.
GET MEDICAL HELP. SKIN-REMOVE CONTAMINATED CLOTHES. FLUSH WITH
WATER THEN WASH WITH SOAP & WATER. GET MEDICAL HELP. INHALED-REMOVE
TO FRES H AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GIVE
OXYGEN IF BREATHING DIFIFCULT. CALL DOCTOR IMMEDIATELY. INGETED-IF
CONSCIOUS, WASH MOUTH OUT WITH WATER. CALL DOTOR IMMEDIATELY.

Flash Point Method:CC
Flash Point:144F,62C
Autoignition Temp:Autoignition Temp Text:700F
Lower Limits:1
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL,
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. PREVENT CONTACT WITH SKIN AND EYES. COOL FIRE
EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:CONTAINER EXPLOSION MAY OCCUR UNDER FIRE
CONDITIONS. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:EVACUATE AREA. ISOLATE AND DENY ENTRY. WEAR
SCBA, RUBBER BOOTS, & HEAVY RUBBER GLOVES. WEAR DISPOSABLE
COVERALLS. AVOID INHALATION. ABSORB ON SAND OR VERMICULITE AND
PLACE IN CLOSED CONTAINER FOR DISP OSAL. VENTILATE & WASH SPILL
SITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:HANDLE & STORE UNDER NITROGEN. KEEP
CONTAINER CLOSED. SOTRE IN A COOL, DRY PLACE. KEEP AWAY FROM
INCOMPATIBLE MATERIALS AND SOURCES OF IGNITION.
Other Precautions:DO NOT BREATH VAPOR. DO NOT GET IN EYES, ON SKIN OR
CLOTHING. WEAR APPROPRIATE PROTECTIVE CLOTHING INCLUDING RUBBER OR
NEOPRENE GAUNTLET GLOVES, SAFETY GOGGLES, NIOSH/MSHA APPROVED
RESPIATOR, FACESHIE LD, OTHER PROTECTIVE CLOTHES.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE LOCAL EXHAUST OR LAB HOOD TO MAINTAIN EXPOSURE
BELOW TLV(S).
Protective Gloves:RUBBER OR NEOPRENE GAUNTLET.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:FACESHIELD, DISPOSABLE COVERALLS, RUBBER
BOOTS, EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
TARGET ORGANS: BLOOD, CENTRAL NERVOUS SYSTEM, LIVER, KIDNEYS, SPLEEN.

HCC:T3
Boiling Pt:B.P. Text:379F,193C
Melt/Freeze Pt:M.P/F.P Text:34.7F,1.5C
Spec Gravity:0.956
Appearance and Odor:YELLOW TO BROWNISH, OILY LIQUID; IRRITATING ODOR.

ACIDS, ACID ANHYDRIDES, OXIDIZING AGENTS, CHLOROFORMATES, HALOGENS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
AVOID SOURCES OF IGNITION AND INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.

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particular situation.